In the first leg, Chelsea travels to Real Madrid on Tuesday night, while PSG hosts Manchester City on Wednesday.
Ferdinand believes PSG will win the final on May 29 in Istanbul, and that there will be no all-English final.
“I think Paris Saint-Germain will win it,’ he predicted on his Rio Ferdinand Presents FIVE YouTube channel.
“They have the experience of last season, two strikers, the business end of the season they know what it’s about now.
“They’ve been here together, they’re not fazed and I think they’ll have the experience. Pochettino comes up smelling of roses after a turbulent couple of years.”